An improved density-based model for the solubility of some compounds in supercritical carbon dioxide

作者：Bian, Xiaoqiang^*; Du, Zhimin; Tang, Yong

来源：Thermochimica Acta, 2011, 519(1-2): 16-21.

DOI：10.1016/j.tca.2011.02.023

• Solubility
• Carbon dioxide
• Supercritical fluid
• Density-based models
• AARD

The ability to correlate the solubility of solutes in supercritical fluids (SCF) is of great importance for the design and evaluation of any supercritical process. The empirical equations are quite successful in correlating the solubility of compounds in the SCF. In this work, a new density-based semi-empirical model was proposed to correlate some compounds in supercritical carbon dioxide. Solubility data from 54 different compounds were collected from literature published in the last ten years and the different empirical models (Chrastil, Adachi-Lu, del Valle-Aguilera, Kumar-Johnston, Mendez Santiago-Teja, Gordillo, Jouyban, Sparks, Garlapati-Madras, and Ch-Madras) were evaluated. The results showed that, the proposed model produced the least global average absolute relative deviation (5.91%) compared to all other empirical models considered in this study.

• 出版日期2011-5-20
• 单位西南石油大学