A four coordinate parent imide via a titanium nitridyl

作者：Tran Ba L; Washington Marlena P; Henckel Danielle A; Gao Xinfeng; Park Hyunsoo; Pink Maren; Mindiola Daniel J^*

来源：Chemical communications, 2012, 48(10): 1529-1531.

DOI：10.1039/c1cc14574f

Treatment of d(1) [(nacnac)TiCl(Ntol(2))] with NaN3 results in NaCl formation and N-2 ejection to yield the first four coordinate, parent imide [(nacnac)Ti=NH(Ntol(2))] (nacnac(-)=[ArNC(CH3)](2)-CH, Ar = 2,6-iPr(2)C(6)H(3), tol = 4-CH3C6H4).

• 出版日期2012