A novel hybrid supercapacitor based on spherical activated carbon and spherical MnO2 in a non-aqueous electrolyte

作者：Wang, Hong-Qiang; Li, Ze-Sheng^*; Huang, You-Guo; Li, Qing-Yu; Wang, Xin-Yu

来源：Journal of Materials Chemistry, 2010, 20(19): 3883-3889.

DOI：10.1039/c000339e

• DOUBLE-LAYER CAPACITORS
• ELECTROCHEMICAL CHARACTERIZATION
• AQUEOUS SUPERCAPACITORS
• RECHARGEABLE BATTERIES
• COMPOSITE ELECTRODE
• MESOPOROUS CARBON
• CATHODE MATERIAL
• ANODE MATERIAL
• OXIDE
• PERFORMANCE

A novel non-aqueous hybrid supercapacitor was fabricated from two spherical materials-an activated mesocarbon microbead (AMCMB) and MnO2 nanowire-sphere, as the negative and positive electrodes, respectively. The preliminary results for this energy-storage device, which operates over a wide voltage range (0.0-3.0 V) using 1 M Et4NBF4 in acetonitrile (AN) as electrolytes, are presented. On the basis of a single electrode, the AMCMB vertical bar MnO2 supercapacitor displays a high specific capacitance of 228 F g(-1) at a scan rate of 10 mV s(-1), corresponding to specific energy of 128 W h kg(-1) based on based on the total mass of active materials, while maintaining desirable cycling stability and rate capability. The combination of the spherical AMCMB and MnO2 in a non-aqueous electrolyte is proved to be suitable for high-performance hybrid supercapacitor applications.

• 出版日期2010
• 单位中南大学; 广西师范大学