Undecacarbonyl-1 kappa C-3,2 kappa C-4,3 kappa C-4-[tris(2-chloroethyl) phosphite-1 kappa P]-triangulo-triruthenium(0)

作者：bin Shawkataly Omar^*; Ghani Syed Sauban; Jothiramalingam Rajabathar; Yeap Chin Sing; Fun Hoong Kun

来源：Acta Crystallographica Section E-Structure Reports Online, 2010, 66: M1191-U242.

DOI：10.1107/S1600536810033891

In the title triangulo-triruthenium compound, [Ru-3(C6H12Cl3O3P)(CO)(11)], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. In the crystal structure, the molecules are linked into a one-dimensional column along [100] by intermolecular C-H center dot center dot center dot O hydrogen bonds.

• 出版日期2010-10