A Highly Efficient Turn-On Fluorescent Sensor for Determination of Water in Organic Solvents

作者：Samadi Maybodi Abdolraouf^*; Akhoondi Reza

来源：Journal of Fluorescence, 2012, 22(5): 1217-1222.

DOI：10.1007/s10895-012-1061-1

• Determination of water
• 2,3biphenyl6-amine-bis-(2, 4, 6-trichlorophenyl) oxalate
• Zn2+ ion
• Fluorimetry technique

2, 3 biphenyl quinoxaline 6-amine is a fluorescent compound in some organic solvents with an excitation wavelength at 435 nm and a fluorescence emission at 518 nm. The fluorescence intensity of 2, 3 biphenyl quinoxaline 6-amine is significantly reduced in the presence of bis-(2, 4, 6-trichlorophenyl) oxalate (TCPO) and Zn2+ due to the nonfluorescent complex formation. The low stability of the complex in presence of trace amount of water results in decomposing complex, thereby recovering the photoluminescence of 2, 3 biphenyl quinoxaline 6-amine. Based on this fact, a turn-on fluorescence photoluminescence sensor for determination of water content in organic solvents was introduced for the first time.
The fluorescence intensity of 2, 3 biphenyl quinoxaline 6-amine as a function of water concentration was used as a simple, sensitive and rapid method for determining trace amount of water in some organic solvents such as ethanol and methanol. The obtained results showed a good linear relationship between fluorescence intensity and the water content with a dynamic range of 0.0094 -1(v/v%), related coefficient of 0.9922 and limit of detection of 0.0026(v/v%). %).

• 出版日期2012-9