Modelling Nd-isotopes with a coarse resolution ocean circulation model: Sensitivities to model parameters and source/sink distributions

作者：Rempfer Johannes^*; Stocker Thomas F; Joos Fortunat; Dutay Jean Claude; Siddall Mark

来源：Geochimica et Cosmochimica Acta, 2011, 75(20): 5927-5950.

DOI：10.1016/j.gca.2011.07.044

The neodymium (Nd) isotopic composition (epsilon(Nd)) of seawater is a quasi-conservative tracer of water mass mixing and is assumed to hold great potential for paleoceanographic studies. Here we present a comprehensive approach for the simulation of the two neodymium isotopes (143)Nd, and (144)Nd using the Bern3D model, a low resolution ocean model. The high computational efficiency of the Bern3D model in conjunction with our comprehensive approach allows us to systematically and extensively explore the sensitivity of Nd concentrations and epsilon(Nd) to the parametrisation of sources and sinks. Previous studies have been restricted in doing so either by the chosen approach or by computational costs. Our study thus presents the most comprehensive survey of the marine Nd cycle to date.
Our model simulates both Nd concentrations as well as epsilon(Nd) in good agreement with observations. epsilon(Nd) covaries with salinity, thus underlining its potential as a water mass proxy. Results confirm that the continental margins are required as a Nd source to simulate Nd concentrations and epsilon(Nd) consistent with observations. We estimate this source to be slightly smaller than reported in previous studies and find that above a certain magnitude its magnitude affects epsilon(Nd) only to a small extent. On the other hand, the parametrisation of the reversible scavenging considerably affects the ability of the model to simulate both, Nd concentrations and epsilon(Nd). Furthermore, despite their small contribution, we find dust and rivers to be important components of the Nd cycle. In additional experiments, we systematically varied the diapycnal diffusivity as well as the Atlantic-to-Pacific freshwater flux to explore the sensitivity of Nd concentrations and its isotopic signature to the strength and geometry of the overturning circulation. These experiments reveal that Nd concentrations and epsilon(Nd) are comparatively little affected by variations in diapycnal diffusivity and the Atlantic-to-Pacific freshwater flux. In contrast, an adequate representation of Nd sources and sinks is crucial to simulate Nd concentrations and epsilon(Nd) consistent with observations. The good agreement of our results with observations paves the way for the evaluation of the paleoceanographic potential of epsilon(Nd) in further model studies.

• 出版日期2011-10-15
• 单位中国地震局