Phenylhydrosilocane as a source of silatranylium cations

作者：Kochina T A; Avrorin V V; Fundamensky V S; Ignatyev I S

来源：Russian Chemical Bulletin, 2016, 65(4): 1047-1052.

DOI：10.1007/s11172-016-1411-2

• cations with the atrane structure
• three-coordinate cations
• silatranylium ions
• germatranylium ions
• phenylhydrosilocane
• nuclear chemical synthesis

Quantum chemical calculations were used for comparative analysis of the cations of the atrane structure [M(OCH2CH2)(3)N](+) (M = Si or Ge) with classic three-coordinate cations R3M+ of Group 14 elements. The possibility of nuclear chemical generation of atranylium cations in the condensed phase was experimentally demonstrated with silatranylium ions as examples.

• 出版日期2016-4