A linear single-molecule magnet based on [Ru-III(CN)(6)](3-)

作者:Pedersen Kasper S*; Dreiser Jan; Nehrkorn Joscha; Gysler Maren; Schau Magnussen Magnus; Schnegg Alexander; Holldack Karsten; Bittl Robert; Piligkos Stergios; Weihe Hogni; Tregenna Piggott Philip; Waldmann Oliver; Bendix Jesper
来源:Chemical communications, 2011, 47(24): 6918-6920.
DOI:10.1039/c1cc12158h

摘要

We report the synthesis, structure and magnetic properties of the first molecular cluster and single-molecule magnet to incorporate [Ru-III(CN)(6)](3-). Frequency-domain Fourier-transform THz-EPR (FDFT THz-EPR) and magnetic susceptibility measurements indicate strongly anisotropic Mn-Ru exchange interactions.

  • 出版日期2011