Double loading of ZnCl2 by polytopic ligands which co-extract Zn2+ and tetrachloridozincate

作者：Lin Tai; Gasperov Vesna; Smith Kate J; Tong Christine C; Tasker Peter A^*

来源：Dalton Transactions, 2010, 39(41): 9760-9762.

DOI：10.1039/c0dt00577k

Combining cation-and anion-binding functionalities in a salen-type extractant leads to multiple loading of ZnCl2. Zn(II) cations are bound by the salen N2O22- donor set, and chlorozincate anions are associated with protonated pendant amine groups.

• 出版日期2010