A Tandem Controlled Radical Polymerization Technique for the Synthesis of Poly(4-vinylpyridine) Block Copolymers: Successive ATRP, SET-NRC, and NMP

作者：Zhou, Yin Ning; Chen, Zhi Chao; Wei, Chuan^*; Luo, Zheng Hong

来源：Macromolecular Chemistry and Physics, 2015, 216(3): 329-333.

DOI：10.1002/macp.201400483

• atom transfer radical polymerization
• block copolymers
• nitroxide-mediated polymerization
• poly(4-vinylpyridine)
• single-electron-transfer nitroxide-radical-coupling

Poly(methyl methacrylate)-block-poly(4-vinylpyridine), polystyrene-block-poly(4-vinyl pyridine), and poly(ethylene glycol)-block-poly(4-vinylpyridine) block copolymers are synthesized by successive atom transfer radical polymerization (ATRP), single-electron-transfer nitroxide-radical-coupling (SET-NRC) and nitroxide-mediated polymerization (NMP). This paper demonstrates that this new approach offers an efficient method for the preparation of 4-vinylpyridine-containing copolymers.

• 出版日期2015-2-2
• 单位上海交通大学