A novel mixed valent Cu-II-Cu-I 2D framework made of a hydrazone and mu-SCN bridged metallacyclic loops cross-linked by mu(3)-SCN chains

作者：Sadhukhan Dipali; Rizzoli Corrado; Garribba Eugenio; Gomez Garcia Carlos J; Yahia Ammar Akram; Charbonniere Loic J; Mitra Samiran^*

来源：Dalton Transactions, 2012, 41(38): 11565-11568.

DOI：10.1039/c2dt31666h

A mixed valent copper complex [(CuCuI)-Cu-II(L)(mu-SCN)(mu(3)-SCN)](n) (LH = N%26apos;-((pyridin-2-yl)methylene)acetohydrazide) has been synthesized and characterized. It is a unique example of a 2D mixed valent Cu-II-Cu-I interlinked molecular assembly with a very unusual bridging property of the hydrazone ligand. An extraordinary in situ partial Cu-II -%26gt; Cu-I reduction is observed in this system at room temperature.

• 出版日期2012