Nitrogen-doped porous carbons through KOH activation with superior performance in supercapacitors

作者：Zhou, Min; Pu, Fan; Wang, Zhao; Guan, Shiyou^*

来源：Carbon, 2014, 68: 185-194.

DOI：10.1016/j.carbon.2013.10.079

• PHENOL-FORMALDEHYDE CARBON
• HIGH-SURFACE-AREA
• ELECTROCHEMICAL CAPACITORS
• ELECTRODE MATERIAL
• NITRIDE MATERIALS
• FUNCTIONAL-GROUPS
• FACILE SYNTHESIS
• ENERGY-STORAGE
• CO2 CAPTURE
• NANOTUBES

A series of nitrogen-doped porous carbons are prepared through KOH activation of a nonporous nitrogen-enriched carbon which is synthesized by pyrolysis of the polymerized ethylenediamine and carbon tetrachloride. The porosity and nitrogen content of the nitrogen-doped porous carbons depend strongly on the weight ratio of KOH/carbon. As the weight ratio of KOH/carbon increases from 0.5 to 2, the specific surface area increases from 521 to 1913 m(2) g(-1), while the nitrogen content decreases from 10.8 to 1.1 wt.%. The nitrogen-doped porous carbon prepared with a moderate KOH/carbon weight ratio of 1, which possesses a balanced specific surface area (1463 m(2) g(-1)) and nitrogen content (3.3 wt.%), exhibits the largest specific capacitance of 363 F g(-1) at a current density of 0.1 A g(-1) in 1 M H2SO4 aqueous electrolyte, attributed to the co-contribution of double-layer capacitance and pseudocapacitance. Moreover, it shows excellent rate capability (182 F g(-1) remained at 20 A g(-1)) and good cycling stability (97% capacitance retention over 5000 cycles), making it a promising electrode material for supercapacitors.

• 出版日期2014-3
• 单位华东理工大学