Probing the molecular environment using spin-resolved photoelectron spectroscopy

作者:Turri G*; Snell G; Langer B; Martins M; Kukk E; Canton SE; Bilodeau RC; Cherepkov N; Bozek JD; Kilcoyne AL; Berrah N
来源:Physical Review Letters, 2004, 92(1): 013001.
DOI:10.1103/PhysRevLett.92.013001

摘要

Angle- and spin-resolved photoelectron spectroscopy with linearly and circularly polarized synchrotron radiation were used to study the electronic structure of model triatomic molecules, hydrogen sulfide, and carbonyl sulfide. The spin-polarization measurements of the molecular field split components of the S 2p photolines revealed a strong effect of the different molecular environments. The validity of simple atomic models to explain the results is discussed.

  • 出版日期2004-1-9