科研之友
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摘要
In the presence of a nickel(0) catalyst, cyclobutanones reacted with diynes to produce bicyclic eight-membered ring ketones. Cyclobutanones acted its it C4 unit in the formal [4+2+2]-type annulation reaction, which proceeded through a ring-expansion of it spirocyclic seven-membered oxanickelacycle to a nine-membered nickelacycle via beta-carbon elimination. A similar annulation reaction was also examined with enynes.
- 出版日期2008-7-15
