New nitrite ionic liquid (IL-ONO) and nanoparticles of organosilane-based nitrite ionic liquid immobilized on silica as nitrosonium sources for electrophilic aromatic nitrosation

作者：Valizadeh Hassan^*; Amiri Mohammad; Shomali Ashkan

来源：Comptes Rendus Chimie, 2011, 14(12): 1103-1108.

DOI：10.1016/j.crci.2011.09.012

• Electrophilic aromatic nitrosation
• Task-specific ionic liquid
• Nitrosonium source
• Immobilized nitrite ionic liquid

An improved method for the synthesis of nitrosoarenes has been developed using a new nitrite ionic liquid (IL-ONO) and immobilized nitrite ionic liquid. These ionic liquids play as nitrosonium sources for electrophilic aromatic nitrosation of active aromatics at 0-5 degrees C. Their action was accomplished in water and the satisfactory results were obtained under the mild conditions in short reaction time.

• 出版日期2011-12