Alkylation of phenol with isopropanol over MCM-49 zeolites

作者：Wei Liguo; Shang Yongchen^*; Yang Piaoping

来源：Reaction Kinetics and Catalysis Letters, 2008, 93(2): 265-271.

DOI：10.1007/s11144-008-5251-4

• MCM-49 zeolites
• alkylation
• phenol
• isopropanol
• isopropylphenol

Alkylation of phenol with isopropanol (IPA) was studied over MCM-49 zeolites. The results revealed that proper reaction conditions could effectively suppress secondary reactions, which greatly improved the selectivity to isopropylphenol. Phenol conversion and total selectivity to isopropylphenol of 61% and 70% were achieved, respectively, under reaction conditions of a temperature of 180 degrees C, WHSV of 3.0 h(-1), and IPA/phenol molar ratio of 0.8.

• 出版日期2008
• 单位哈尔滨工程大学; 哈尔滨师范大学