A Cp*CoI2-dimer as a precursor for cationic Co(III)-catalysis: application to C-H phosphoramidation of indoles

作者：Sun Bo; Yoshino Tatsuhiko; Matsunaga Shigeki^*; Kanai Motomu

来源：Chemical communications, 2015, 51(22): 4659-4661.

DOI：10.1039/c4cc10284c

C2-selective indole C-H phosphoramidation was achieved through improved Cp*Co(III) catalysis. A cationic Co(III) species generated in situ from a Cp*CoI2-dimer showed the best catalytic activity, giving phosphoramidated indoles in 60-86% yield.

• 出版日期2015