A 2-D metal-organic framework based on linear trinuclear copper cluster units: syntheses, structures and magnetic properties

作者:Wang Liping; Zhang Erpeng; Zhou Xiaoli; Wang Yufei; Liu Yanli; Li Lingchuan
来源:Journal of Chemical Research, 2018, 42(4): 198-201.
DOI:10.3184/174751918X15233542085919

摘要

<jats:p> The coordination polymer [Cu<jats:sub>3</jats:sub>(tci)<jats:sub>2</jats:sub>(phen)<jats:sub>2</jats:sub>]<jats:sub> n</jats:sub> (H<jats:sub>3</jats:sub>tci = 1,3,5-tris(2-carboxyethyl)isocyanurate; phen = 1,10-phenanthroline) has been synthesised. Single-crystal X-ray diffraction studies have shown that the polymer displays a 2-D metal–organic framework based on linear trinuclear copper cluster units, and its magnetic properties indicate antiferromagnetic interactions. </jats:p>

  • 出版日期2018-4