A highly selective fluorescent probe for Al3+ based on 4-aminoantipyrine

作者:Zhou, Yanmei*; Zhang, Junli; Zhou, Hua; Hu, Xiaoyi; Zhang, Lin; Zhang, Min
来源:Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy , 2013, 106: 68-72.
DOI:10.1016/j.saa.2012.12.084

摘要

A novel and simple Schiff base based on 2-pyridine formaldehyde and 4-aminoantipyrine was synthesized and characterized as a fluorescent probe. In the presence of Al3+, the fluorescent intensity has a dramatic enhancement over other examined metal ions in aqueous solution. The method of Job's plot indicated the formation of 1:1 complex between probe and Al3+, and the possible binding mode of the system was also proposed. Moreover, other examined metal ions had no effect on the detection of Al3+.