A new mixed divalent metal phosphate with zeolite thomsonite framework topology

作者：Ke YX^*; He GF; Li JM; Zhang YG; Lu SM

来源：New Journal of Chemistry, 2001, 25(12): 1627-1630.

The synthesis and crystal structure of [Zn(10-x)Cox(PO4)(8)(HPO4)(2)](C3N2H12)(4)(H2O)(3) (x approximate to 3.45) (ZCP-THO), which is the first mixed cobalt and zinc phosphate with zeolite THO topology, are described. ZCP-THO is characterized by means of single-crystal and powder X-ray diffraction. The structure has a 3-D 8-ring channel system with protonated 1,3-propanediamine cations and water molecules occupying the channel junctions. The structure collapsed after the removal of the organic template by heating.

• 出版日期2001
• 单位中国科学技术大学