Dual graphs realized in the compounds di-mu(3)-4-mercaptopyridine catena-di-mu(2)-iodo-di-mu(3)-iodo-mu(4)-iodo penta copper(I) and di-mu(3)-4-mercaptopyridine-di-catena-iodo-di-mu(3)-iodo tri copper(I)

作者：Jalilian Ehsan^*; Lidin Sven

来源：Journal of Solid State Chemistry, 2010, 183(11): 2656-2661.

DOI：10.1016/j.jssc.2010.09.009

• Copper(I)
• Iodide
• Structure
• Cluster

Two compounds, [Cu5I5](SNC5H4)2 [i] and [Cu3I3](SNC5H4)2 [ii], were synthesized under hydrothermal conditions and the crystal structures were solved. Both compounds crystallized in space group 141/a. The iodide and the sulphur from mercaptopyridine are connected to copper atom, giving the copper atoms tetrahedral coordination geometry. The pyridine end of the organic moiety is non-bonding and fills the empty space around the tetrahedra formed from copper, sulphur and iodide.

• 出版日期2010-11