A butenolide intermediate in methylenomycin furan biosynthesis is implied by incorporation of stereospecifically C-13-labelled glycerols

作者:Corre Christophe; Haynes Stuart W; Malet Nicolas; Song Lijiang; Challis Gregory L*
来源:Chemical Communications, 2010, 46(23): 4079-4081.
DOI:10.1039/c000496k

摘要

The label from [3-C-13]-L-glycerol is incorporated into the hydroxymethyl group of methylenomycin furans suggesting a butenolide intermediate in their biosynthesis.

  • 出版日期2010