摘要
A two-dimensional zinc(II) coordination polymer, {[Zn(C8H4O4)(C2H8N2)].3H(2)O}(n), has been constructed from zinc(II), 1,3-benzenedicarboxylic acid and ethylenediamine. Within the polymer, each Zn atom is coordinated by two monodentate 1,3-benzenedicarboxylate ligands and two ethylenediamine ligands which define a distorted tetrahedral geometry. The two-dimensional network is further held together by pi-pi stacking interactions and hydrogen-bonding interactions, giving two types of extended one-dimensional channels along the a axis with dimensions of 10.207 (1) x 7.286 (1) Angstrom and 10.207 (1) x 6.240 (1) Angstrom.
- 出版日期2003-10
- 单位厦门大学