A two-dimensional coordination polymer, mu-1,3-benzenedicarboxylato-mu-ethylenediamine-zinc(II) trihydrate

作者:Jiang, YQ*; Xie, ZX; Ng, SW
来源:Acta Crystallographica Section E-Structure Reports Online, 2003, 59: M947-M949.
DOI:10.1107/S1600536803020579

摘要

A two-dimensional zinc(II) coordination polymer, {[Zn(C8H4O4)(C2H8N2)].3H(2)O}(n), has been constructed from zinc(II), 1,3-benzenedicarboxylic acid and ethylenediamine. Within the polymer, each Zn atom is coordinated by two monodentate 1,3-benzenedicarboxylate ligands and two ethylenediamine ligands which define a distorted tetrahedral geometry. The two-dimensional network is further held together by pi-pi stacking interactions and hydrogen-bonding interactions, giving two types of extended one-dimensional channels along the a axis with dimensions of 10.207 (1) x 7.286 (1) Angstrom and 10.207 (1) x 6.240 (1) Angstrom.