High-yield graphene exfoliation using sodium dodecyl sulfate accompanied by alcohols as surface-tension-reducing agents in aqueous solution

作者：Yeon Changbong; Yun Sun Jin^*; Lee Kyu Sung; Lim Jung Wook

来源：Carbon, 2015, 83: 136-143.

DOI：10.1016/j.carbon.2014.11.035

The exfoliation of graphite was investigated in aqueous solutions containing sodium dodecyl sulfate (SDS) as a surfactant. The exfoliation was greatly enhanced near the surface aggregation concentration (SAC) of SDS, 2.6 mM, and then decreased for higher SDS contents. However, the flakes exfoliated near the SAC were graphite, whereas graphene was obtained above the critical micelle concentration (CMC). The effect of the use of alcohols as surface-tension-reducing agents (STRAs) on the exfoliation was then investigated. With ethyl alcohol, a dispersion of 2.1 mg ml(-1) graphene was achieved from 2.6 mM SDS after only 1 h of sonication, whereas a dispersion of 0.2 mg ml(-1) was obtained above the CMC in the absence of STRAs. The results demonstrate that the SDS content near the SAC is highly beneficial for exfoliation as long as the surface tension is maintained near 41.0 mN ml(-1). This finding supports the notion that the structure of the adsorbed SDS, depending on its concentration, strongly affects the exfoliation of graphite into graphene.

• 出版日期2015-3