Aqueous electrosynthesis of an electrochromic material based water-soluble EDOT-MeNH2 hydrochloride

作者：Sun, Hui; Zhang, Long; Dong, Liqi; Zhu, Xiaofei; Ming, Shouli; Zhang, Youshan; Xing, Huakun; Duan, Xuemin^*; Xu, Jingkun^*

来源：Synthetic Metals, 2016, 211: 147-154.

DOI：10.1016/j.synthmet.2015.11.019

• Conducting polymer
• Aqueous solution
• Electrochemical polymerization
• PEDOT derivative
• Electrochromic

2'-Aminomethyl-3,4-ethylenedioxythiophene (EDOT-MeNH2) showed unsatisfactory results when its polymerization occurred in organic solvent in our previous report. Therefore, a water-soluble EDOT derivative was designed by using hydrochloric modified EDOT-MeNH2 (EDOT-MeNH2 center dot HCl) and electropolymerized in aqueous solution to form the corresponding polymer with excellent electrochromic properties. Moreover, the polymer was systematically explored, including electrochemical, optical properties and structure characterization. Cyclic voltammetry showed low oxidation potential of EDOT-MeNH2 center dot HCl (0.85 V) in aqueous solution, leading to the facile electrodeposition of uniform the polymer film with outstanding electroactivity. Compared with poly(2'-aminomethyl-3,4-ethylenedioxythiophene) (PEDOT-MeNH2), poly(2'-aminomethyl-3,4-ethylenedioxythiophene salt) (PEDOT-MeNH(3)(+)A(-)) revealed higher efficiencies (156 cm(2) C-1), lower bandgap (1.68 eV), and faster response time (1.4s). Satisfactory results implied that salinization can not only change the polymerization system, but also adjust the optical absorption, thereby increase the electrochromic properties.

• 出版日期2016-1
• 单位江西科技师范大学