A novel 2D metal-organic framework with Lewis basic sites as a heterogeneous base catalysis

作者：Guo, Feng^*; Yuan, Binfang; Shi, Wenbing

来源：Inorganic Chemistry Communications, 2017, 86: 285-289.

DOI：10.1016/j.inoche.2017.11.007

• Metal-organic framework
• Lewis basic sites
• Catalysis
• Knoevenagel reaction

A 2D metal-organic framework, [(Nd-2(TATMA)(2)center dot 4DMF center dot 4H(2)O](n) (namely NdTATMA), was successfully assembled from a semi-rigid organic ligand 4,4,4 ''-s-triazine-1,3,5-triyltri-m-aminobenzoate (H(3)TATMA) and Nd(III) ion. NdTATMA has binuclear (Nd-2(COO)(6)} inorganic clusters and completely deprotonated organic ligands. In the topology view, NdTATMA can be simplified as a 3,6-connected kgd topology with the Schlafli symbol of (4(3))(2)(4(6).6(6).8(3)). This resultant sample has been fully characterized by single crystal and powder X-ray diffractions, elemental analysis and thermogravimetric analyses. Due to abound Lewis basic sites in the structure, NdTATMA can be served as a good heterogeneous base catalysis to catalyse Knoevenagel condensation reaction. The resultant sample is able to recycle four times without significant activity decrease.

• 出版日期2017-12
• 单位长江师范学院