A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes

作者：Oliveri Christopher G; Heo Jungseok; Nguyen SonBinh T^*; Mirkin Chad A; Wawrzak Zdzislaw

来源：Inorganic Chemistry, 2007, 46(19): 7716-7718.

DOI：10.1021/ic701424j

We report a highly convergent and modular approach for the synthesis of dissymmetric cofacial porphyrin complexes, which is based upon the weak-link approach to supramolecular coordination chemistry. Specifically, we have utilized a halide-induced ligand rearrangement reaction, which is capable of providing heteroligated mixed-metal porphyrin complexes in quantitative yield. Significantly, the adoption of a coordination chemistry based approach for the synthesis of these complexes allows for facile in situ regulation of the porphyrin-porphyrin interactions through the addition of external chemical stimuli.

• 出版日期2007-9-17
• 单位西北大学