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摘要
Graphene oxide (GO) was reduced by formaldehyde or formic acid in vapor or liquid phases below 200 degrees C. The influence of the concentrations of reducing agents, reaction temperature and time on the electrical conductivity of the reduced graphene oxide (rGO) was investigated. The rGOs were characterized by XRD, XPS and Raman spectroscopy. Results show that the optimum reaction temperatures are 150 and 175 degrees C in the vapor phase and the liquid phase, respectively, based on the electrical conductivities of the rGOs. The ratio of the areas of the C ls peaks related to the C-C and C-O (R-cc/co) from XPS decreases with reaction time from 9 to 24 h in the vapor phase, and increases from 2 to 24 h in the liquid phase, which are in agreement with the electrical conductivities and Raman results. Gasification of carbon atoms in GO sheets may be responsible for the decrease of R-cc/co with prolonged reaction time in the vapor phase.
- 出版日期2017-2
- 单位山西大学
