Ultra-thin and uniform coating of vanadium oxide on multiwall carbon nanotubes through solution based approach for high-performance electrochemical supercapacitors

作者：Shakir Imran^*; Choi Joon Hyock; Shahid Muhammad; Shahid Shaukat Ali; Rana Usman Ali; Sarfraz Mansoor; Kang Dae Joon

来源：Electrochimica Acta, 2013, 111: 400-404.

DOI：10.1016/j.electacta.2013.07.156

• Bottom up approach
• Ultra-thin film
• Energy storage devices
• Vanadium oxide
• Multi walled carbon nanotubes

Electrochemical supercapacitors based on metal oxide nanostructures are poised to provide integration of power sources onto electronic devices, but they suffer from poor cycle lifetime, as well as low energy and power density. To tackle these problems, we report a simple, low-cost, safe and broadly applicable hierarchical bottom-up assembly route for the formation of ultrathin (3 nm) vanadium oxide (V2O5) film on conducting MWCNTs. The ultrathin V2O5 shows a very high capacitance of 510 Fg(-1) and possesses excellent cyclic stability with negligible decrease in specific capacitance after 5000 cycles. The supercapacitor device based on this hierarchical bottom-up assembly exhibit an excellent charge/discharge capability, and energy densities of 16 Wh kg(-1) at a power density of 800 W kg(-1). Such high performances are due to both the high crystallinity and complete accessibility of ultra-thin film of V2O5 to the aqueous electrolyte of 2 M KCl.

• 出版日期2013-11-30