Unusual crystal and molecular structure of the 1-(1-silatranylmethyl)-3,5-dimethylpyrazole complex with zinc dichloride

作者：Voronkov M G^*; Zel'bst E A; Fundamenskii V S; Bruskov V A; Kashaev A A; Soldatenko A S; Bolgova Yu I; Trofimova O M

来源：Journal of Structural Chemistry, 2011, 52(4): 828-830.

DOI：10.1134/S0022476611040305

• 1-(1-silatranylmethyl)-3,5-dimethylpyrazole complex with zinc dichloride
• molecular structure
• X-ray diffraction

The crystal and molecular structure of a 1-(1-silatranylmethyl)-3,5-dimethylpyrazole complex with zinc dichloride (I) is determined by XRD. The coordination polyhedron of the zinc atom is a tetrahedron formed by two covalent Zn-Cl bonds and coordination Zn a dagger N and Zn a dagger O bonds. Compound I is the first example of how an endocyclic oxygen atom of the silatranyl fragment participates in the coordination of the metal atom with the formation of a six-membered heterocycle.

• 出版日期2011-8