A luminescent europium metal-organic framework with free phenanthroline sites for highly selective and sensitive sensing of Cu2+ in aqueous solution

作者：Zhang, Li-Na; Liu, Ai-Ling; Liu, Ya-Xing; Shen, Jia-Xiu; Du, Chen-Xia^*; Hou, Hong-Wei

来源：Inorganic Chemistry Communications, 2015, 56: 137-140.

DOI：10.1016/j.inoche.2015.04.003

• Europium metal-organic framework
• Luminescence
• Sensor
• Phenanthroline
• Cu2+

A luminescent europium metal-organic framework [Eu(HL)(L)(H2O)(2)]center dot 2H(2)O (1) (H2L = (2,3-f)-pyrazino(1,10)phenanthroline-2,3-dicarboxylic acid) with uncoordinated phenanthroline nitrogen sites was hydrothermally synthesized. It exhibits highly sensitive and selective sensing of Cu2+ in aqueous solution. To the best of our knowledge, complex 1 is the first luminescent Eu-MOF with uncoordinated phenanthroline nitrogen sites for selective sensing of Cu2+ in aqueous solution. The probable sensing mechanism was discussed in detail.

• 出版日期2015-6
• 单位河南理工大学; 郑州大学