Anion Exchange in Cationic Frameworks: Structures of Channel-Forming Triarylpyrylium Tetrafluoroborate Salts

作者：Wiscons Ren A^*; Zeller Matthias; Rowsell Jesse L C

来源：Crystal Growth & Design, 2016, 16(4): 2201-2210.

DOI：10.1021/acs.cgd.6b00005

The crystal structure of a co-crystal of 2,4,6-tris(4-methylphenyl)pyridine and 2,4,6-tris(4-methylphenyl)pyrylium revealed a pseudohexagonal motif assembled from pi-stacked helices that enclose 1-D channels containing disordered tetrafluoroborate counterions and solvent molecules. Though convoluted by disorder, aperiodicity, and complex twinning patterns, further investigation was motivated by the unique packing arrangement of this material, which enables solid-state anion diffusion, while resisting dissolution in water. Such properties are ideal for the development of anion exchange materials that can be employed for the remediation of agricultural and nuclear waste. To develop a more complete understanding of the intermolecular interactions that give rise to this helical motif, we have compiled and analyzed the local interactions and extended structural motifs of 19 pore- and channel-forming 2,4,6-triarylpyrylium crystal structures. Three conserved local interactions were identified, including C-H center dot center dot center dot X- interactions, the rhombic binding pocket, and four-ring antiparallel dimerization. Development of this library of interaction motifs rationalizes the packing arrangement of the co-crystal and contributes to the informed design of anion exchange materials.

• 出版日期2016-4