A new chiral diiron catalyst for enantioselective epoxidation

作者：Marchi Delapierre Caroline; Jorge Robin Adeline; Thibon Aurore; Menage Stepphane^*

来源：Chemical communications, 2007, (11): 1166-1168.

DOI：10.1039/b616172c

The dinuclear chiral complex Fe2O(bisPB)(4)(X)(2)(ClO4)(4) (X = H2O or CH3CN) catalyzes with high efficiency (up to 850 TON) and moderate enantioselectivity (63%) the epoxidation of electron deficient alkenes at 0 degrees C by a peracid.

• 出版日期2007
• 单位中国地震局