mu-Decanedioato-bis[aquabis(1,10-phenanthroline-kappa N-2,N ')manganese(II)] dinitrate-sebacic acid-water (1/1/2)

作者：Feng, Ye-Qiang; Long, Jian; Li, Juan^*

来源：ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2011, 67: M80-+.

DOI：10.1107/S1600536810051615

In the title complex, [Mn-2(C10H16O4)(C12H8N2)(4)(H2O)(2)]-(NO3)(2)center dot C10H18O4 center dot 2H2O, the asymmetric unit contains one-half of the centrosymmetric dinuclear complex cation, one uncoordinated water molecule, one-half of a free sebaic acid (decanedioic acid) molecule that is also completed by inversion symmetry, and one disordered nitrate anion [occupancy ratio 0.454 (4): 0.544 (6)]. The Mn-II atoms are each octahedrally surrounded by four N atoms from two 1,10-phenanthroline (phen) ligands, one O atom from one carbonyl group of the bridging sebacate ligand and one O atom of a water molecule. The crystal structure is stabilized by intermolecular O-H center dot center dot center dot O hydrogen bonds.

• 出版日期2011-1
• 单位贵州师范大学