Novel Bis-fused pi-Electron Donor Composed of Tetrathiafulvalene and Tetraselenafulvalene

作者：Ashizawa Minoru; Ishidzu Ken ichi; Watanabe Masaki; Tanahashi Tetsuhiko; Shirahata Takashi; Kawamoto Tadashi; Mori Takehiko; Misaki Yohji^*

来源：Chemistry Letters, 2010, 39(10): 1093-1095.

DOI：10.1246/cl.2010.1093

A new donor (ST-STP), in which tetrathiafulvalene and tetraselenafulvalene are fused, has been synthesized. This donor shows unexpectedly large on-site Coulomb repulsion compared with other bis-fused TTF systems In (ST-STP)ReO4, intramolecular charge disproportionation is suggested by the crystal structure and transport properties.

• 出版日期2010-10-5