A Ru-isocyanate initiator for fast, living, precisely controlled ring-opening metathesis polymerization at ambient temperatures

作者：Monfette Sebastien; Marleau Gillette Joshua; Conrad Jay C; McDonald Robert; Fogg Deryn E^*

来源：Dalton Transactions, 2012, 41(48): 14476-14479.

DOI：10.1039/c2dt32568c

The new complex Ru(NCO)(2)(IMes)(py)(2)(=CHPh) is the first ruthenium metathesis initiator capable of fast, controlled living polymerization of functionalized norbornenes at room temperature, irrespective of monomer bulk.

• 出版日期2012