A new intermediate in spontaneous styrene polymerisation inhibited by 2-nitrophenol

作者:Thatcher Robert J; Newby Thomas E; Price Peter; Loyns Colin; Chechik Victor*
来源:RSC Advances, 2014, 4(66): 35131-35136.
DOI:10.1039/c4ra05443a

摘要

The polymerisation inhibitor, 2-nitrophenol reacts with radicals generated in self-initiated thermal styrene polymerisation to form the unexpected benzoxazine 1. We propose the mechanism for the formation of 1 and show that it is produced by a radical mediated C-H activation.

  • 出版日期2014

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