A quinoline-polyamine conjugate as a fluorescent chemosensor for quantitative detection of Zn(II) in water

作者:Shiraishi Yasuhiro*; Ichimura Chizuru; Hirai Takayuki
来源:Tetrahedron Letters, 2007, 48(44): 7769-7773.
DOI:10.1016/j.tetlet.2007.09.032

摘要

A simple ligand (L1), a diethylenetriamine bearing two end quinoline fragments, was synthesized. Without metal cations, L1 shows no fluorescence at pH 2-13; however, Zn2+ addition creates strong fluorescence at pH 5-12. The emission intensity exhibits linear and stoichiometrical response to the Zn2+ amount. No remarkable emission enhancement was, however, observed for other cations.

  • 出版日期2007-10-29