Acid-Catalyzed Synthesis of alpha,beta-Disubstituted Conjugated Enones by a Meyer-Schuster-Type Rearrangement in Allenols

作者：Alcaide Benito^*; Almendros Pedro; Cembellin Sara; Martinez del Campo Teresa

来源：Advanced Synthesis & Catalysis, 2015, 357(5): 1070-1078.

DOI：10.1002/adsc.201400928

• alcohols
• allenes
• Bronsted acids
• homogeneous catalysis
• Lewis acids

A novel, direct and simple methodology to gain access to alpha,beta-disubstituted conjugated enones from alpha-allenols in a sustainable metal catalysis context, considering the inexpensiveness and environmentally friendliness of iron(III) species and protons, has been developed.

• 出版日期2015-3-23