Direct evidence for reversible diffusional phase change in nanometer-sized alloy particles

作者：Lee JG^*; Mori H

来源：Physical Review Letters, 2004, 93(23): 235501.

DOI：10.1103/PhysRevLett.93.235501

Solid solubility in isolated nanometer-sized particles has been studied by in situ transmission electron microscopy using alloy particles in the Pb-Sn binary system. In approximately 17-nm-sized particles of a lead-56 at. % Sn solid solution, a phase change from a single phase of the lead solid solution to two phases, a lead solid solution and a tin-solid solution, takes place when the temperature is reduced from 110 degreesC to room temperature (RT). Furthermore, it is confirmed that this phase change could occur rather reversibly when the temperature is cyclically changed between 110 degreesC and RT. This observation provides direct evidence for reversible diffusional phase change in nanometer-sized alloy particles. It seems safe to conclude that the solubility limit of tin in lead is higher than 56 at. % at 110 degreesC, which is almost 5 times higher than the solubility limit of tin in bulk lead (i.e., 10 at. %).

• 出版日期2004-12-3