A renewable copper electrode as an amperometric flow detector for nitrate determination in mineral water and soft drink samples

作者：Gamboa Juan C M; Pena Roselyn C; Paixao Thiago R L C; Bertotti Mauro^*

来源：Talanta, 2009, 80(2): 581-585.

DOI：10.1016/j.talanta.2009.07.028

• Nitrate
• Nitrite
• Flow injection analysis
• Renewable copper surface
• Mineral water
• Soft drink

A novel approach was developed for nitrate analysis in a FIA configuration with amperometric detection (E=-0.48 V). Sensitive and reproducible current measurements were achieved by using a copper electrode activated with a controlled potential protocol. The response of the FIA amperometric method was linear over the range from 0.1 to 2.5 mmol L(-1) nitrate with a detection limit of 4.2 mu mol L(-1) (S/N = 3). The repeatability of measurements was determined as 4.7% (n=9) at the best conditions (flow rate: 3.0 mL min(-1), sample volume: 150 mu L and nitrate concentration: 0.5 mmol L(-1)) with a sampling rate of 60 samples h(-1). The method was employed for the determination of nitrate in mineral water and soft drink samples and the results were in agreement with those obtained by using a recommended procedure. Studies towards a selective monitoring of nitrite were also performed in samples containing nitrate by carrying out measurements at a less negative potential (-0.20 V).

• 出版日期2009-12-15