A novel activated nitrogen-containing carbon anode material for lithium secondary batteries

作者：Liu, Enhui^*; Shen, Haijie; Xiang, Xiaoxia; Huang, Zhengzheng; Tian, Yingying; Wu, Yuhu; Wu, Zhilian; Xie, Hui

来源：Materials Letters, 2012, 67(1): 390-393.

DOI：10.1016/j.matlet.2011.09.112

• Activated carbon
• X-ray photoelectron spectroscopy
• Electrical properties
• Lithium secondary batteries

A novel activated nitrogen-containing carbon anode material has been prepared by carbonization and activation of phenol-melamine-formaldehyde resin which is synthesized by the condensation polymerization method. The physicochemical properties of the carbon were characterized by scanning electron microscope, X-ray diffraction, Raman spectra, Brunauer-Emmett-Teller, elemental analysis and X-ray photoelectron spectroscopy measurement. Lithium storage performances have been analyzed by galvanostatic charge/discharge and cycle performance. The carbonization sample shows a first discharge capacity of 515 mAh g(-1). After activation, the first discharge capacity is up to 917 mAh g(-1), the reversible capacity is still as high as 251 MAh g(-1) after 20 cycles. It may be a promising candidate as anode material for lithium secondary batteries.

• 出版日期2012-1-15
• 单位湘潭大学