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A lvt-type Framework [Cu-2(tza)(4)]center dot ClO4 center dot 4H(2)O Derived from 1H-tetrazole-1-acetic Acid
Ma, Li
Peng, Guo
Cai, Jin Biao
Deng, Hong
Zeller, Matthias
Zeitschrift fur Anorganische und Allgemeine Chemie, 637(6), pp 755-758, 2011-5
Summary
The reaction of 1H-tetrazole-1-acetic acid (Htza) and perchloric acid with cuprous chloride with slow evaporation at room temperature gave a novel 3D porous Cu-II coordination polymer, [Cu-2(tza)(4)]center dot ClO4 center dot 4H(2)O (1), (tza = tetrazole-1-acetate). The structure exhibits an unusual 3D microporous coordination framework built up by four coordinated CuII nodes and bidentate bridging tza ligands with lvt-type topology. Furthermore, the magnetic properties of complex 1 were also investigated.
Keywords
1H-tetrazole-1-acetic acid; Magnetic properties; lvt Topology; Porous; Coordination polymer
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