A lvt-type Framework [Cu-2(tza)(4)]center dot ClO4 center dot 4H(2)O Derived from 1H-tetrazole-1-acetic Acid
Zeitschrift fur Anorganische und Allgemeine Chemie, 2011, 637(6): 755-758.
The reaction of 1H-tetrazole-1-acetic acid (Htza) and perchloric acid with cuprous chloride with slow evaporation at room temperature gave a novel 3D porous Cu-II coordination polymer, [Cu-2(tza)(4)]center dot ClO4 center dot 4H(2)O (1), (tza = tetrazole-1-acetate). The structure exhibits an unusual 3D microporous coordination framework built up by four coordinated CuII nodes and bidentate bridging tza ligands with lvt-type topology. Furthermore, the magnetic properties of complex 1 were also investigated.
1H-tetrazole-1-acetic acid; Magnetic properties; lvt Topology; Porous; Coordination polymer