Miniemulsion cross-linking: A convenient route to hollow polymeric nanocapsule with a liquid core

作者：Wu, Lin^*; Pang, Tao; Guan, Ye-bin

来源：Chinese Journal of Polymer Science, 2016, 34(5): 523-531.

DOI：10.1007/s10118-016-1784-6

• Cross-linking
• Miniemulsion
• Nanocapsule
• Block copolymer

Miniemulsion stabilized by poly(2-(dimethylamino) ethyl methacrylate)-block-poly(butyl methylacrylate) (PDMAEMA-b-PBMA) diblock copolymers has been used as liquid templates for the synthesis of polymer nanocapsules via quaternization cross-linking of PDMAEMA segments of the copolymer by 1,2-bis(2-iodoethoxy)ethane (BIEE) crosslinkers. PDMAEMA-b-PBMAs here as a stabilizer in miniemulsion with different molecular weights led to a size variation in diameters of nanocapsules, demonstrating the capsules have potential design capability of this technique. The solution behavior of the capsules has been also investigated in this paper.

• 出版日期2016-4
• 单位安庆师范大学