The role of mixing entropy in molecular self-assembly

作者：Evstigneev Maxim P^*; Buchelnikov Anatoly S

来源：Chemical Physics Letters, 2013, 567: 48-49.

DOI：10.1016/j.cplett.2013.02.062

It has been shown that for the case of linearly polymerizing systems in solution the contribution from mixing entropy should not be taken into account when the dependence of equilibrium constant on the number of molecules in an aggregate must be explicitly considered. A correction to the published profiles of equilibrium constant is suggested.

• 出版日期2013-4-19