A 3D Zn(II) coordination polymer with a new semi-rigid tripodal ligand tecton showing 4-connected three-fold interpenetrating diamond network and helical character

作者：Zhang Hong Na; Yuan Fei; Hu Huai Ming^*; Shen Sa Sa; Xue Gang Lin

来源：Inorganic Chemistry Communications, 2013, 34: 51-54.

DOI：10.1016/j.inoche.2013.05.002

• Coordination polymer
• Terpyridine derivative
• Helical chain
• Interpenetration
• Luminescent property

A new zinc coordination polymer [Zn(L)(2)](n) (1) (HL = 4'-(4-carboxy-methoxyphenyl)-4,2':6',4 ''-terpyridine) was constructed under hydrothermal condition. X-ray single diffraction studies reveal that 1 shows a three-fold interpenetrating 3D framework with a 4-connected dia topological net, which contains the same number of left- and right-handed 2(1) helical chains. Additionally, photoluminescence property of 1 has been investigated.

• 出版日期2013-8
• 单位西北大学