A novel CuII-azido-pyrazine framework with 3D-42.63.8-topology: Crystal structure and magnetic property

作者：Luo, Yang-Hui; Lu, Yong-Hong; Sun, Bai-Wang^*

来源：Inorganica Chimica Acta, 2013, 404: 188-191.

DOI：10.1016/j.ica.2013.04.018

• Cu-II-azido-pyrazine
• Methyl groups control
• Magnetic property

The methyl groups of 2,3-dimethylpyrazine (2,3-DMP) in [Cu-2(N-3)(4)(2,3-DMP)](n) (1) lead to the formation of a novel 3D-4(2).6(3).8-topology, which exhibits 2D honeycomb layer completed by Cu-II ions, di-EO and di-EE azido, and featuring strong antiferromagnetic coupling.

• 出版日期2013-8-1
• 单位东南大学