An Unprecedented Decanuclear GdIII Cluster for Magnetic Refrigeration

作者：Liu, Sui-Jun; Zhao, Jiong-Peng; Tao, Jun; Jia, Ji-Min; Han, Song-De; Li, Yue; Chen, Yan-Cong; Bu, Xian-He^*

来源：Inorganic Chemistry, 2013, 52(16): 9163-9165.

DOI：10.1021/ic400487m

• SINGLE-MOLECULE-MAGNET
• DY
• LN
• COMPLEX
• FIELD

An unprecedented decanuclear Gd-III cluster composed of the [Gd-10(mu(3)-OH)(8)](22+) core has been hydrothermally synthesized. Magnetic analyses indicate that this complex shows weak antiferromagnetic behavior with a relatively large magnetocaloric effect (-Delta S-m(max) = 31.22 J kg(-1) K-1).

• 出版日期2013-8-19
• 单位中山大学; 厦门大学; 南开大学