Hydrothermal synthesis of sphere-like BiOCl using sodium lignosulphonate as surfactant and its application in visible light photocatalytic degradation of rodamine B

作者：Hao, Chen^*; Xu, Yimei; Bao, Mengjiao; Wang, Xiaohong^*; Zhang, Huailiang; Li, Tihai

来源：Journal of Materials Science: Materials in Electronics , 2017, 28(4): 3119-3127.

DOI：10.1007/s10854-016-5900-8

• TEXTILE WASTE-WATER
• ONE-POT SYNTHESIS
• ASSISTED SYNTHESIS
• ZNO
• PERFORMANCE
• NANOSTRUCTURES
• NANOCOMPOSITES
• COMPOSITE
• REMOVAL
• GROWTH

The BiOCl-SL was prepared by a simple hydrothermal reaction between Bi(NO3)(3)center dot 5H(2)O and KCl using sodium lignosulfonate (SL) as a structure-directing agent. The standard tetragonal structure of the BiOCl has been confirmed by X-ray powder diffraction. The scanning electron microscopy results revealed that a suitable amount of SL is favorable for the formation of hollow sphere-Like BiOCl. The fourier transform infrared spectroscopy (FT-IR) of the BiOCl-SL showed the BiOCl samples have been cleaned thoroughly, and the following photocatalytic experiment will not be affected by SL. In comparison with the pure BiOCl, the UV-Vis diffuse reflectance spectroscopy (UV-Vis-DRS) of the BiOCl-SL showed a red shift of absorption edge. The Brunauer-Emmett-Teller surface area measurement indicated that the surface area of BiOCl-SL is much bigger than that of pure BiOCl. The photocatalytic activity of BiOCl was tested on the degradation of Rodamine B (RhB) under visible light irradiation, and the result showed that the BiOCl-SL-0.3 had excellent photocatalytic activity for RhB after visible light irradiation for 2 h.

• 出版日期2017-2
• 单位江苏大学