Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-kappa N-2(3),O-4)iron(II)

作者:Du, Chao-Jun*; Song, Xing-Hua; Wang, Li-Sheng; Du, Chao-Ling
来源:Acta Crystallographica Section E-Structure Reports Online, 2011, 67: M997-U1638.
DOI:10.1107/S1600536811024779

摘要

In the title compound, [Fe(C5H3N2O4)(2)(H2O)(2)], the Fe-II ion lies on an inversion centre and is coordinated by two N and two O atoms from two 5-carboxy-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral geometry. An intramolecular O-H center dot center dot center dot O hydrogen bond occurs. In the crystal, intermolecular N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds form a three-dimensional network, which consolidates the packing.

全文